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samsung kies
http://www.samsung.com/uk/support/usefulsoftware/KIES/
if you connect Samsung Galaxy Ace to PC Drag down the notification bar and tap on "USB Connected" and accept the prompts to connect the phone in mass storage mode, then open my computer locate the phone check the folder DCIM .
http://devicesupport.swisscom.ch/web/samsung-galaxy-ace-plus/connectivity-synchronisation/how-to-transfer-files-between-your-computer-and-mobile-phone